.., .., ..

(65), N- (66) , (67):

2= + MeCOSH I\ (|

"lite life <62>

' ! +SOCh I

MeCOS-Ch^CHCOOH MeCOSCH2CHCOCI (63) /1 (64) ,

Av NHVMeOH is.

OCCH(Me)CH2SCOMe (66)

0=CCH(Me)CH2SH (67)

- - AcNH2

97

" 2 2. Pd/C

(69) Na(CN)BH3

(70) N- --- (68) 2--4- (69):

OCCH(MB)NH2 (68)

0=OCH-NHCHCOEI

I I

Me CH2CH2Ph (70)

5.3.2.2.

-

(71), ( (73),

(75), (74)].

( ), , .

(71) 5

(72).

(73) |3-(2-)-5] (74) (5-), .

(75), :

-^2<; 2- CH2CH2-NH2

3- (81), , ( , ).

.

. . (78) 3-- (79) . , (80). (80) - (81):

F 1 /20, _ ~\ >2

(78)

N Me (80)

^NH-NH2 ^ 2/''' /, X * 3 "

\--sU. >, (8l)

0=-4-1-

NaH/

N

(73)

(71, 3Hrio2.H20 (?2 2

,

20

(7+) (75)

, , - 3- 1- (77), . 1- (76) :

(76) Me

I* J \ * NH2NHCNH2 II J X S

N

(77) Me

98

(86), - .

, ( ). (82), - N- - (83). - (84). (84) - , . - , (85). (85) 99

5.3.2.3.

1970- () . -, (, , , ), . (4epei , ) .

, , (87). -, , .

36
< > 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63

" " (1.27Mb)


[]  []  [ ]  [-]  []  [ ]

 

 


30 seconds to mars 2018

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.

- . , , , , , , . , , , , , , , . , , , , , , , . , . , , , . , 1972 .

 

 



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